A New Route for the Synthesis of 1,4-Dicarbonyl …

Giri, R.; Yu, J.-Q.
"Synthesis of 1,2 and 1,3-dicarboxylic Acids via Pd(II)-Catalyzed Carboxylation of" Aryl and Vinyl C-H Bonds""
J.

1,4-Diketone synthesis by C-C coupling - Organic chemistry

1,3-Diketone synthesis - Organic chemistry

K.; Yu, J-.Q.
"Synthetic Applications of Pd(II)-Catalyzed C-H Carboxylation and Mechanistic Insights: Expedient Routes to Anthranilic Acids, Oxazolinones and Quinazolinones."
J.

A special group of carbonyl compounds are 1,3-dicarbonyl ..

Two synthetic methods for tetra- and trisubstituted -H pyrroles are presented: (i) the thermal pyrrole formation by the reaction of vinyl azides with 1,3-dicarbonyl compounds via the 1,2-addition of 1,3-dicarbonyl compounds to 2-azirine intermediates generated in situ from vinyl azides; (ii) the Cu(II)-catalyzed synthesis of pyrroles from α-ethoxycarbonyl vinyl azides and ethyl acetoacetate through the 1,4-addition reaction of the acetoacetate to the vinyl azides. By applying these two methods, regioisomeric pyrroles can be prepared selectively starting from the same vinyl azides.


α-Bromoketone synthesis by bromination

Dynamic kinetic resolution in asymmetric synthesis - Wikipedia

5-hydroxymethyl furfural 67-47-0 - The Good Scents …